@Fenderchris
It is annoying to have an issue that's hard to explain and figure out.
I have explained why there are differences in your images above. It's because one is set on Windows audio and the other not. The dropdown menus you have in one but not in the other only appear, when ASIO is selected. If both are set to the same setting, then the layout is the same. Nothing in your images show that anything is wrong.
Your issue is, that you for some reason can't select ASIO for your Pigments without it crash. But as i wrote, then this is clearly not a common issue.
There is this thread about similar issue:
https://forum.arturia.com/index.php?topic=93767.0You can try to delete this folder and try again: "C:\ProgramData\Arturia\Pigments\tmp (This should have been done allready, if your uninstall was full. But does'nt harm to try.)
I can only suggest, what i allready have suggested in my posts - including contacting Arturia and RME support directly, if nothing else helps.
We don't know about Arturias coding.
I presume you have only Pigments open to use your RME soundcard, when you try to select the ASIO driver.